SMT assembly is an optimization process. There is no single stencil printing process for all PWB designs. The stencil printing parameters of stencil design, squeegee speed, snap off speed, stencil wipe frequency, and solder paste for assembling all PWBs will not be the same; just as there is no single reflow oven profile for all PWBs. Fortunately, most solder paste specifications give good boundaries for all of these parameters, but typically some trial and error experiments will be needed when assembling a new PWB design that is not similar to past assemblies.
The need for optimization is most obvious when trying to minimize defects. As an example, minimizing graping is often facilitated by using a ramp to peak reflow profile. However, the ramp to peak profile may acerbate voiding. See Figure 1.
Figure 1. The ramp to peak reflow profile may minimize graping, but acerbate voiding.
Thankfully your SMT soldering materials and equipment suppliers deal with these optimization issues on a daily basis. So if you are ever stuck with some challenging SMT assembly process, contact these solder materials and equipment experts first.
Imagine you are Guglielmo Marconi, and you opened the first radio factory in Chelmsford England in 1912. Using Lee De Forest’s 1906 invention, the triode vacuum tube, your early radios needed a way to connect the various electronic components together. Enter soldering. Soldering is the most cost effective and reliable, some might say only, way to connect electronic components together. It has been since the birth of electronics with the radio.
It is interesting to ponder some of the effects that the radio had on civilization and society. Before the radio, most of the United States was disconnected. People in California didn’t know what was happening in New York in anything like real time. There was also no national entertainment. Following early broadcasts in the 1920s, radio was a staple of most American homes by the 1930s. Families would gather around the radio after dinner to listen to the news and comedy, drama, music, etc. This golden age of radio lasted from the 1920s through the 1950s until radio was supplanted by television. See Figure 1.
Figure 1. A young girl listens to the radio in the 1930s. It would be difficult to overstate the impact of radio…all enabled by soldering.
Electronic soldering, in a sense, is a miracle of technology. It enables connecting copper to copper at a temperature of less than 230°C. The connection is reversible, conducts electricity well, and is mechanically strong. This soldering temperature is crucial for electronics, as the printed wiring boards and component packages contain polymer materials that cannot withstand temperatures much higher than 230°C. This low soldering temperature is especially impressive when considering that to bond copper to copper without solder would require temperatures near that of the melting point of copper or 1085°C.
To work its magic, solder forms intermetallics with copper. See Figure 2. The intermetallic closest to the copper is rich in Cu3Sn, and that closest to the solder is rich in Cu6Sn5.
Figure 2. A schematic cross section of a component lead soldered to a PWB pad.
It is important that the soldering bond is reworkable. The electronics industry would have difficulty being profitable without this important feature of soldering as most assembly processes have some yield loss that requires rework.
So, the next time you use your smartphone, PC, or TV, remember it wouldn’t be possible without the miracle of soldering.
Figure 1 source: By Franklin D. Roosevelt Library Public Domain Photographs – This media is available in the holdings of the National Archives and Records Administration, cataloged under the National Archives Identifier (NAID) 195876., Public Domain, https://commons.wikimedia.org/w/index.php?curid=2151524
You are putting in a new assembly line to assemble some large boards for which your company just received a three-year contract. The boards are 45cm long and you expect the cycle time from the component placement machines to be 40 seconds per board. Your boss is pressuring you to get another 5-zone oven, as they are cheaper and take up much less space than a 7- or 10-zone oven. But, you are concerned that a 5-zone oven may not have the capacity that is needed to keep up with the component placement machines. Let’s make some calculations and see if your concerns are justified.
Table 1 shows some typical reflow oven metrics:
Let’s assume that you will be using a typical modern SAC solder paste. By studying the reflow profile above, we see that the amount of time needed in the heated zone is about 4.5 min. or 270 sec.
So if we choose the 5-zone oven the belt speed will be:
Belt Speed = BS= Heat Tunnel Length/Time in Heated Tunnel = HTL/Time = 180 cm/270 sec. or 0.66 cm/sec
The component placers will be presenting a 45cm board every 40 sec., so the belt speed needs to be:
Pity Ötzi, The Iceman, circa 3500 BC. It is believed that he was involved in copper smelting as both copper particles and arsenic, a trace element in some copper ores, were found in his hair. Not only was he being slowly poisoned by the arsenic, but to smelt the copper he had to achieve a wood fire temperature of about 1085ºC (1985ºF), as discussed in my last post. The arsenic in the copper did have a benefit, as it gave the copper a little more strength than if it were pure.
Shortly after Otzi’s time, metal workers discovered that adding 10% tin to the copper produced bronze. Bronze is not only markedly harder than copper, but it melts at almost 100ºC lower than pure copper, making metal working much easier. The Bronze Age had begun. This period coincided with what scholars would recognize as the beginning of modern civilizations, such as those in Egypt and Greece.
Since it melts at a lower temperature, bronze also fills molds better. This improved mold filling is evident in Figure 1. This photo shows a copper and bronze hatchet that I had made. The copper hatchet on the left shows evidence of poor mold filling.
Figure 1. Copper, on the left, and bronze hatchets that were made for Dr. Ron’s Dartmouth College course ENGS 3: Materials: The Substance of Civilization. Note that the copper hatchet shows poor mold filling due to copper’s higher melting temperature..
In my opinion, it is almost certain that the Bronze Age is related to the development of soldering. The first evidence of soldering was about 3000º BC where, arguably the first civilization, the Sumerians assembled their swords with high temperature solders. Since the base metal for most copper-to-copper soldering is tin, the early metal workers almost certainly learned that tin could be used to join copper or bronze pieces together at much lower temperatures than smelting.
Until the European Union’s restrictions on lead in solders in 2006, most electronics solders were tin-lead eutectic. Eutectic is a Greek word that roughly translates into “easy melting.” Figure 2 shows the tin-lead phase diagram. Note that the melting point of tin is 232ºC and that of lead is 327ºC, yet at the eutectic concentration of 63% tin/37% lead, the melting temperature drops to 183ºC. This concentration and temperature is known as the eutectic point.
Figure 2. The tin-lead phase diagram. Note the eutectic point at 183ºC.
After the EU’s lead restriction went into effect, most electronics solders are based on a tin-silver-copper alloy that melts in the 217-225ºC range. The most common of these alloys being SAC305 (Sn96.5Ag3.0Cu0.5, where the numbers are weight percentages.)
Although the eutectic point is an interesting and usually beneficial phenomenon due to its lower melting point, the true miracle of soldering is that two pieces of copper that melt at 1085ºC can be bonded together with a tin-based solder at less than 232ºC. The value of this benefit cannot be overstated. Nature has allowed us to mechanically and electrically bond two pieces of copper together at a low enough temperature that we can do this bonding in the presence of electrically insulating polymer materials. Without this feature of solder, we would not have the electronics industry! An added benefit is that the bonding is reworkable, so that if a component fails, it can be replaced without scrapping the entire electronics printed circuit board.
Soldering is an ancient technology. It is estimated that soldering was first discovered as long ago as 4000 BC. So soldering was much more ancient to Julius Caesar (100 BC – 44 BC) than Caesar is to us today. Before considering soldering, let’s discuss early copper smelting, as copper is usually the metal soldered to.
My Cornell colleague Steve Sass wrote a book, Materials: The Substanceof Civilization, on which I based my course of the same name on. In his book, Sass points out that the importance of the firing of clay can’t be overstated as it is the first time humankind changed the nature of a material. Once clay is fired it forms ceramic, a material much stronger than dried clay. Artisans first performed this feat about 26,000 years ago in what is now the Czech Republic.
While I agree with Sass’s assessment, it could also be argued that the beginning of modern technology can be traced back to the first smelting of copper. The firing of clay is too simple a process to encourage much further experimentation, which is needed for technology growth. The process of smelting of copper, the first metal liberated from its ore, is quite complex and this complexity led to further experimentation that gave us iron and steel. Continued working with metals likely developed the scientific method, hence led up to all of the breakthroughs to this day.
Consider the novelty of the first smelting of copper. To smelt copper, our ancestors had to grind copper ore, malachite (Figure 1), into a powder, mix it with carbon, and heat it to greater than 1085ºC (1985ºF). By the way, you can estimate the Fahrenheit temperature by multiplying the Celsius temperature by a factor of two and will only be off by <10% from 100º-1700ºC.
Figure 1. Malachite (copper ore) is quite attractive. Perhaps this attractiveness brought it to our ancient ancestors’ attention as a candidate for smelting. (Copyright 2018, Ronald C. Lasky, Indium Corp.)
After I cook on my outdoor grill, I clean the grates by turning the propane to maximum to cook off the grease. Typically the grill’s thermometer will read about 600ºF during this process. The grill gives off so much heat that it is oppressive to approach it to turn it off. Needless to say, noting what 600ºF feels like suggested to me that it is very hard to achieve 1985ºF with a wood or charcoal fire.
Anyway, I recruited some graduate students to try and smelt copper as described above. They purchased many bags of charcoal, used a leaf blower to supply air and worked for two hours on two different attempts and failed both times. The next year some students built a tower with vents and put charcoal on the bottom with the copper ore and carbon in a crucible on top. Their tower was similar to a roman smelting furnace for iron (Figure 2). They were successful and produced a piece if copper about the size of a penny.
Figure 2. A Roman style furnace. Dr. Ron’s students built a similar tower from cinderblocks.
These two attempts demonstrate how amazing our distant ancestors were. How did they think to do it? There were certainly many failed attempts. How did they persevere? One thing is certain, they started the trend of discovery, in about 5000 BC, that led us to today. We owe them much.
In my last post, I discussed intermetallic compounds (IMCs) and what I referred to as the “miracle of soldering.” I also mentioned that research focused on the brittle nature of IMCs suggests that failures in stress tests are more likely due to failures between the interfaces of the IMCs and the solder, the IMCs and the copper, or the IMCs (Cu6Sn5 with Cu3Sn) themselves and are not related to any perceived brittle nature of the IMCs.
Another weakening mechanism in soldering and thermal aging of solder joints is Kirkendall voids. Kirkendall voids form when one metal diffuses more rapidly into another metal than vice versa. A copper-tin interface displays such a mechanism. Copper diffuses into the tin more rapidly than the tin into the copper. This mechanism can result in actual voids in the copper at the metal interface. See the image below. In addition to causing a possible weakness at the interface, the excess copper that diffuses into the tin creates compressive stresses than can result in tin whiskers.
IMCs and Kirkendall voids are formed quite quickly at soldering temperatures. However, even at room temperature IMCs and Kirkendall voids continue to grow, albeit at a much reduced rate. The reason for this continued growth is that on the absolute temperature or Kelvin scale, room temperature is a considerable fraction of the melting temperature of solders. As an example, the melting temperature of SAC is about 219°C, this temperature is equal to 492K (219+273), whereas room temperature is 295°K, so room temperature is 60% of the way to the melting point of SAC solder (295/492 = 0.60). Compare this situation to steel, which melts at about 1480°C. The steel would be red hot at 60% (780°C) of its melting point on the absolute scale. So, since room temperature is 60% of the way to melting, the IMC and Kirkendall forming processes don’t stop at room temperature. Hence, IMCs and Kirkendall voids continue to grow, as do related effects such as tin whiskers.
Stay tuned. Next time we will discuss IMC growth rates and resulting effects in stress testing as we wrap up this series on IMCs.
This PCB assembly challenge involved attaching a solar panel to one side of a pad using solder paste with a pass through an SMT reflow soldering oven.
Solder wicking through the unmasked vias to the back side forms unacceptable “bumps” on top of the vias.
The attachment or bond itself wasn’t the issue; but after the first trial runs, it was clear that solder wicking through the unmasked vias was going to be. Solder would wick through the unmasked vias to the back side and form “bumps” on top of the vias.
These bumps made the surface nonplanar and of course were unacceptable. It wasn’t an issue of using excess solder paste. But the “wicked wicking” had to be stopped, or at least prevented.
Kapton tape is applied to cover the unmasked vias; it will block the molten solder from leaking through.
But how? Clearly, to keep the solder where we wanted it to remain during reflow, we had to find a way to prevent it from wicking up, collecting at the opposite ends of the vias and forming bumps. We had to find a solution that was simple, temporary, and tolerant of reflow soldering temperatures. The answer was Kapton polyimide tape, a familiar product to PCB assemblers for many years, and a material that does not degrade at reflow temperatures.
Kapton tape was applied to cover the unmasked vias in order to block the molten solder from leaking through the vias to the back side during reflow. After reflow and cooling, it was a simple matter to peel off the tape. This temporary masking solution worked; there were no more solder bumps on the back side of the assembly, and the cost of the fix in terms of time and material was very low.
Figure 3. This temporary masking solution worked; there are no more solder bumps on the back side of the assembly.
If you missed the SMTA International preshow webinar supported by CIRCUITS ASSEMBLY you can view it online here.
Printing solder paste or other conductive material requires zero defects printing if a high first-pass yield is to be achieved when using fine-pitch components. Monitoring and control of paste height and volume are becoming the norm in many markets, but what capability can we expect?
Correct printer setup, good stencil design and manufacture plus consistent printing materials are key to successful manufacture but inspection and monitoring the performance makes a process more robust. The same three-dimensional inspections are required in other AOI applications like solder joint analysis. There are common process defects during printing and reflow, Willis says, and the webinar shows causes and cures to help yield improvement.
Figure 1 shows a closeup photo of a PCB assembly, it seems as though solder has flowed “down the drain” and away from the solder joint where it’s needed.
In fact it has, because the customer has inconveniently located a via right through the center of one of the two topside SMT pads for a surface mount component. When the assembled PCB is run through reflow, the molten solder drains away through the barrel of the via and out the other side of the PCB. There isn’t enough solder remaining post-reflow to create an acceptable solder joint per IPC-A-610. The joint is “starved”; this is unacceptable. What to do?
Figure 1. Insufficient solder, i.e., “starved” solder joint on an SMD pad.
The via is there to stay, by virtue of the customer design. So, no matter how many times solder is added to the joint, every time the PCB is run through the reflow oven the solder is going to drain away because the PCB , including the via, is at reflow temperature.
Obviously, more than one run through the oven makes no sense. The only practical solution is to manually add solder to the individual solder joint, post-reflow, without running the entire PCB through another thermal cycle. It’s a touchup procedure that’s required to create a robust SMT solder joint that meets acceptability criteria. This is a manual PCB assembly soldering process that should be performed by a skilled hand-soldering or rework operator. Solder is added only to the joint, via cored wire solder or solid wire with flux, in order to build up the volume of solder at the solder joint to provide strength, connectivity, and an acceptable meniscus per IPC standards, covering the via drain-hole. The solder won’t flow through the via because only the surface joint area is heated.
Figure 2. The solution: Add solder to the joint manually via a touchup procedure.
It may seem tedious, but a skilled operator can touch up the joint in a few seconds, and if there is only one instance per assembly it won’t appreciably cause production delays.
I’m a bit behind in my blog work — well, way behind, actually. I started this series back in January with the intro post.
Here’s where I am right now:
I have three different sets of PCBs.
One set, I took home to see if it’s possible to solder a micro-BGA at home. (As someone working at a car manufacturer might want to see if they could balance a crankshaft at home, for fun)
Two sets, from our partner, Sunstone Circuits, are here in my desk with parts, ready to go through our machines.
After I’ve got all three sets built, I’ll have them x-rayed to see how they look under the hood. Finally, I’ll solder through-hole headers on and fire up the chips to see if the shared escape system works.
Here’s one of the boards without access to the inner pads:
And, here’s the shared escape:
The main concern I have is that Reset is on one of the inside pins (B4). I’m not sure if I can get the chip to a state where it will operate properly without unobstructed access to reset.
The routing I’ve chosen is probably the only possible option for reset. Pin A4, right above, is used for the single-wire debug (SWD) clock. I’m assuming that can’t be shared. B5 is Vdd, so that’s out. It might be possible to go down. C4 defaults to one of the crystal pins, and D4 defaults to a disabled state.
In the route I’ve chosen, B3 is an ADC input, so it should start out high-impedance, and therefore not interfere. A3 defaults disabled, so it won’t get in the way.
Next step: solder time!
One other thing – The images above show non-solder mask defined (NSMD) pads. Those are standard for BGAs 0.5mm pitch and higher. This part is 0.4mm pitch. Some manufacturers recommend solder mask defined pads (SMD) for 0.4mm and smaller. I’m actually testing several pad styles: SMD, NSMD and solder mask opening = copper.